SYNTHESIS OF [TRIAQUA-µ3-OXIDO-HEXA(3- HYDROXYBENZOATO)TRIIRON(III)] CHLORIDE DIHYDRATE
DOI:
https://doi.org/10.5281/zenodo.17406914Abstract
A newly synthesized iron(III) coordination compound, [Fe₃(O)(C₇H₅O₃)₆(H₂O)₃]·Cl·2H₂O (Compound 1), was successfully prepared and structurally characterized. The complex was obtained by reacting FeCl₃·6H₂O with m- hydroxybenzoic acid under mild hydrothermal conditions. X-ray diffraction analysis revealed that the compound crystallizes in a triclinic system featuring a trinuclear Fe³⁺ core bridged by a central μ₃-oxo atom and surrounded by six m-hydroxybenzoate ligands
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